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T-Butyl Bromoacetate

T-Butyl Bromoacetate

CAS: 5292-43-3

Molecular Formula: C6H11BrO2

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T-Butyl Bromoacetate - Names and Identifiers

Name T-Butyl Bromoacetate
Synonyms T-BUTYL BROMOACETATE
T-Butyl Bromoacetate
tert-Butylbromoacetate
tert-Butyl bromoacetate
t-Butyl 2-bromo acetate
Tert-butyl bromo acetate
tert-Butyl 2-bromoacetate
tert-Butyl α-bromoacetate
tertiary butyl bromoacetate
bromoacetic acid T-butyl ester
1,1-Dimethylethyl bromoacetate
2-Bromoacetic acid-t-butylester
1,1-Dimethylethyl 2-bromoacetate
Bromoacetic acid tert-butyl ester
CAS 5292-43-3
EINECS 226-133-6
InChI InChI=1/C6H11BrO2/c1-6(2,3)9-5(8)4-7/h4H2,1-3H3
InChIKey BNWCETAHAJSBFG-UHFFFAOYSA-N

T-Butyl Bromoacetate - Physico-chemical Properties

Molecular FormulaC6H11BrO2
Molar Mass195.05
Density1.338
Melting Point44-47 °C
Boling Point50°C10mm Hg(lit.)
Flash Point121°F
Water SolubilityMiscible with ethanol, chloroform and ethyl acetate. Immiscible with water.
Vapor Presure1.62hPa at 25℃
AppearanceLiquid
Specific Gravity1.333 (20/4℃)
ColorClear colorless to yellow
BRN1753010
Storage Condition0-6°C
SensitiveLachrymatory
Refractive Indexn20/D 1.445(lit.)
Physical and Chemical Properties
density 1.208
boiling point 50 ° C. (10 torr)
refractive index 1.444-1.446
flash point 49°C
UseUsed as pharmaceutical intermediates for the synthesis of amino acids and peptide compounds

T-Butyl Bromoacetate - Risk and Safety

Risk CodesR10 - Flammable
R36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24/25 - Avoid contact with skin and eyes.
S16 - Keep away from sources of ignition.
UN IDsUN 1993 3/PG 3
WGK Germany3
FLUKA BRAND F CODES19
TSCAT
HS Code29159080
Hazard NoteIrritant/Flammable/Lachrymatory
Hazard Class3
Packing GroupIII

T-Butyl Bromoacetate - Reference Information

NIST chemical information Information provided by: webbook.nist.gov (external link)
EPA chemical information Information provided by: ofmpub.epa.gov (external link)
use tert-butyl bromoacetate is a common alkylating agent and is a colorless to yellowish transparent liquid in a barrel. Used as a pharmaceutical intermediate.
1. tert-butyl bromoacetate is used as a pharmaceutical intermediate to synthesize amino acids and peptide compounds.
2. tert-butyl bromoacetate is a common alkylating agent. It is used to synthesize collagenase inhibitor (S,S,R)-(-)-actinonin. Construct to replace butyl as the research object.
tert-butyl bromoacetate is used as a pharmaceutical intermediate to synthesize amino acids and peptide compounds.
Conventional alkylation reagents are used to synthesize collagenase inhibitors (S,S,R)-(-)-actinonin; tert-butyl acetate intermediates, etc.
Preparation Prepared by the reaction of bromoacetic acid and thionyl chloride and separated to obtain bromoacetyl chloride, and then reacted with tert-butanol at room temperature.
synthesis method using bromoacetic acid and isobutylene as raw materials, Amberlyst15 strongly acidic cation exchange resin as catalyst, and tert-butanol as additive to synthesize tert-butyl bromoacetate, through orthogonal test, study the effect of 5 solvents on product yield and the inhibition of tert-butanol on isobutylene polymerization, and determine the best process conditions: dichloromethane as solvent, when the reaction time is 6 h, the reaction temperature is 10 ℃, the amount of catalyst is 12g, and the amount of tert-butanol is 4g. The yield of the product reached 94.2%.
Last Update：2024-04-10 22:29:15
T-Butyl Bromoacetate
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Jiangsu Pules Biotechnology Co.,Ltd.
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CAS: 5292-43-3
Tel: 0513-66814854
Email: pules.cn@gmail.com
Mobile: +86-17551318830
JIANGSU BSECHEM CHEMICAL TECHNOLOGY CO., LTD.
Spot supply
Product Name: T-Butyl Bromoacetate Request for quotation
CAS: 5292-43-3
Tel: +86-17505207175
Email: 3787852685@qq.com
Mobile: +86-17505207175
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Nantong Reform Petro-Chemical CO., LTD.
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CAS: 5292-43-3
Tel: +86-13776910623
Email: r@reformchem.com­
Mobile: +86-13776910623
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Shanghai Amole Biotechnology Co., Ltd.
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CAS: 5292-43-3
Tel: 400-968-2212
Email: 3623107365@qq.com
Mobile: 18916960931
QQ: 3623107365 Click to send a QQ message
Wechat: 18916960931
SHANGHAI ACMEC BIOCHEMICAL TECHNOLOGY CO., LTD.
Spot supply
Product Name: tert-Butyl Bromoacetate Visit Supplier Webpage Request for quotation
CAS: 5292-43-3
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922 Click to send a QQ message
Wechat: 18621343501
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SKYRUN INDUSTRIAL CO.,LTD
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Product Name: tert-Butyl bromoacetate Visit Supplier Webpage Request for quotation
CAS: 5292-43-3
Tel: +86 0571-86722205
Email: sales@chinaskyrun.com
Mobile: +8618958170122
QQ: 2531159185 Click to send a QQ messageSend QQ message
Wechat: chinaskyrun
Hefei TNJ Chemical Industry Co.,Ltd.
Product Name: T-Butyl Bromoacetate Request for quotation
CAS: 5292-43-3
Tel: 0086-551-65418684
Email: sales@tnjchem.com
　　　　 info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840 Click to send a QQ message
Wechat: 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Shanghai Worldyang Chemical Co.,Ltd.
Product Name: tert-Butyl bromoacetate Request for quotation
CAS: 5292-43-3
Tel: +86-21-56795779
Email: charles7788@worldyachem.com
Mobile: +86-13651600618
QQ: 2850607228 Click to send a QQ message
Wechat: +8613651600618
WhatsApp: +8613651600618
Zouping Mingxing Chemical Co., Ltd.
Product Name: tert-Butyl bromoacetate Request for quotation
CAS: 5292-43-3
Tel: 0086-13605431940
Email: xuli678323@126.com
Mobile: +86-13605431940
QQ: 56860987 Click to send a QQ message
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View History
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